Continuity of the Levy-Lieb and Lieb functionals

Let ρ,ρnL1(Rd,R+)\rho,\rho_n\in L^1(\mathbb{R}^d,\mathbb{R}_+) satisfy ρ,ρnH1(Rd)\sqrt{\rho},\sqrt{\rho_n}\in H^1(\mathbb{R}^d). The functionals F(0)F^{(0)} and Fmix(0)F^{(0)}_{\mathrm{mix}} denote the pure-state and mixed-state Levy–Lieb functionals, respectively.

Continuity conjecture. If

ρnρin H1(Rd),\sqrt{\rho_n}\to\sqrt{\rho}\quad\text{in }H^1(\mathbb{R}^d),

then

F(0)(ρn)F(0)(ρ)andFmix(0)(ρn)Fmix(0)(ρ).F^{(0)}(\rho_n)\to F^{(0)}(\rho)\quad\text{and}\quad F^{(0)}_{\mathrm{mix}}(\rho_n)\to F^{(0)}_{\mathrm{mix}}(\rho).

The conjecture would imply that pure-state vv-representable ground densities are not dense when d3d\geq 3, using densities where the mixed-state functional is strictly smaller than the pure-state functional. The paper gives no proof or disproof.

Sources & referencesView supporting material

Primary source

Louis Garrigue, “Building Kohn-Sham potentials for ground and excited states”, arXiv:2101.01127 (2022).

Progress summary

Never refreshed

Nothing recorded yet. Refresh searches the literature and the public web for attempts on this problem, and writes the first summary here.

Solutions 0

No solutions have been posted yet.