Product-form characterization for conservative weakly reversible reaction networks

Let (G,κ)(\mathcal{G},\kappa) be a conservative weakly reversible chemical reaction network under mass-action kinetics. Write R\mathcal{R} for its set of reactions, and for each reaction rRr\in\mathcal{R} let νr\nu_r and νr\nu'_r denote its reactant and product complexes. Assume that for every rRr\in\mathcal{R} there is no distinct reaction r~R\tilde r\in\mathcal{R} with

νrνr=νr~νr~.\nu'_r-\nu_r=\nu'_{\tilde r}-\nu_{\tilde r}.

Product-form characterization conjecture. The network (G,κ)(\mathcal{G},\kappa) has a product-form stationary distribution if and only if it is complex balanced.

This conjecture proposes that, under the stated nondegeneracy condition on reaction differences, product-form stationary distributions occur only through complex balance, although the paper exhibits weakly reversible positive-deficiency networks with rate-independent product forms beyond complex balance. Its status is not resolved in the supplied text.

Sources & referencesView supporting material

Primary source

Beatriz Pascual-Escudero and Linard Hoessly, “An algebraic approach to product-form stationary distributions for some reaction networks”, arXiv:2012.03227 (2021).

Additional references

2 papers in this index state this conjecture (2007–2020). The statement above is taken from the most recent of them; the others are arXiv:0711.0493.

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