Weak Mittleman's conjecture for the Dirac–Fock ground state energy

Let eqe_q be the physical ground state energy of the electron-positron Hartree–Fock model and let EqE_q be the ground state energy of the Dirac–Fock model. For α\alpha small and cc large, the two energies satisfy

eqEqeq+oαc0(c2).e_q\leq E_q\leq e_q+o_{\alpha_c\to 0}(c^{-2}).

Weak Mittleman's conjecture. The Dirac–Fock model is an approximation of the electron-positron Hartree–Fock model in the precise sense of the displayed inequality. This weaker statement is introduced because the original conjecture may fail when the relevant eigenvalue is not simple or when the stated spectral-gap condition does not hold. It quantifies the error at order smaller than c2c^{-2} in the indicated nonrelativistic regime.

Sources & referencesView supporting material

Primary source

Long Meng, “A rigorous justification of the Mittleman's approach to the Dirac–Fock model”, arXiv:2301.03431 (2023).

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