The ionization conjecture for atoms

Let HNH_N be the NN-electron atomic Hamiltonian with nuclear charge ZNZ\in\mathbb{N}, and let EN=infσ(HN)E_N=\inf\sigma(H_N). Denote by Nc=Nc(Z)N_c=N_c(Z) the largest number of electrons for which ENcE_{N_c} has a minimizer. Ionization conjecture. There is a constant C>0C>0, possibly C=1C=1, such that

NcZ+C.N_c\leqslant Z+C.

The existence of minimizers for N<Z+1N<Z+1 is known by Zhislin's theorem, while the uniform bound on the number of excess electrons remains open.

Sources & referencesView supporting material

Primary source

Phan Thành Nam, “The ionization problem in quantum mechanics”, arXiv:2206.15393 (2022).

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