Bétermin's conjecture on phase transitions for one-well potentials
Bétermin's conjecture on phase transitions for one-well potentials
Let be a two-dimensional lattice of area , and let denote its lattice energy for a potential . A potential is completely monotone if it satisfies for all , and it is one-well if there exists such that is nonincreasing on and nondecreasing on . A Lennard--Jones type potential has the form , where and . Bétermin's conjecture. The behavior of the minimizers of with respect to the lattice area is qualitatively the same for all Lennard--Jones type potentials, namely, the minimizers undergo hexagonal--rhombic--square--rectangular lattice phase transitions. More generally, the same result should hold for every potential such that and are completely monotone and is one-well. This conjecture extends the known triangular-lattice minimization result for completely monotone potentials to non-monotone one-well potentials and predicts a universal sequence of lattice phase transitions; the general assertion remains open.
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Primary source
Senping Luo and Juncheng Wei, “On minima of difference of theta functions and application to hexagonal crystallization”, arXiv:2203.00264 (2022).
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