Non-product-form conjecture for conservative non-weakly reversible reaction networks

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Let G\mathcal{G} be a conservative, almost essential, non-weakly reversible chemical reaction network under mass-action kinetics. Let R\mathcal{R} be its set of reactions, and let R′⊆R\mathcal{R}'\subseteq\mathcal{R} be a connected component that is not weakly reversible. For each reaction rr, write νr\nu_r and νr′\nu'_r for its reactant and product complexes. Assume that there is a reaction r∈R′r\in\mathcal{R}' such that no reaction r~∈R∖R′\tilde r\in\mathcal{R}\setminus\mathcal{R}', with r~≠r\tilde r\ne r, lies in a weakly reversible component and satisfies

νr′−νr=νr~′−νr~.\nu'_r-\nu_r=\nu'_{\tilde r}-\nu_{\tilde r}.

Non-product-form conjecture. Then G\mathcal{G} has a non-product-form stationary distribution independently of the reaction rate; equivalently, it belongs to class N.

The conjecture is motivated by the non-weakly reversible examples in the paper, for which product-form stationarity fails independently of the rate. No resolution is given in the supplied text.

References

Primary source

Beatriz Pascual-Escudero and Linard Hoessly, “An algebraic approach to product-form stationary distributions for some reaction networks”, arXiv:2012.03227 (2021).

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