Average-height criterion for the order of polymer adsorption transitions

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Let C\mathcal{C} be an infinite subclass of self-avoiding walks in an upper half-plane, with starting point on the surface. For ω∈C\omega\in\mathcal{C}, let h(ω)h(\omega) be the maximum height above the surface reached by ω\omega, and let ⟨hn⟩\langle h_n\rangle be the average of h(ω)h(\omega) over walks ω∈C\omega\in\mathcal{C} of length nn. Average-height criterion. If walks in C\mathcal{C}, equipped with a surface interaction associated with steps along the surface, exhibit an adsorption phase transition, then the transition is first-order if

⟨hn⟩=Θ(n),\langle h_n\rangle=\Theta(n),

and second-order if

⟨hn⟩=O(n3/4).\langle h_n\rangle=O(n^{3/4}).

This is presented as a rough conjectural explanation for why prudent-walk models have first-order transitions, contrasting with models whose average heights grow sublinearly. The criterion is not proved in the paper.

References

Primary source

Nicholas R. Beaton and Gerasim K. Iliev, “A solvable non-directed model of polymer adsorption”, arXiv:1506.06436 (2015).

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