The quantum-classical partition-function inequality

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Let Zq(β,h)=∑n=1∞e−βEn(h)Z_q(\beta,h)=\sum_{n=1}^{\infty}e^{-\beta E_n(h)} be the quantum statistical sum, where En(h)E_n(h) are the energy eigenvalues, and let

Zc(β)=∫∫e−βH(p,q) dp dqZ_c(\beta)=\int\int e^{-\beta H(p,q)}\,dp\,dq

be the classical statistical sum for the Hamiltonian

H(p,q)=12m∑j=1Npj2+V(q).H(p,q)=\frac{1}{2m}\sum_{j=1}^{N}p_j^2+V(q).

Here h>0h>0 is Planck's constant, β>0\beta>0, and NN is the dimension of the coordinate space. Quantum-classical partition-function inequality. The inequality

(2πh)NZq(β,h)≤Zc(β)(2\pi h)^N Z_q(\beta,h)\leq Z_c(\beta)

is true for all h>0h>0 and β>0\beta>0. This extends the Wigner--Kirkwood classical-limit relation from the limit h→0h\to0 to a proposed global inequality, but the source supplies no resolution of the conjecture.

References

Primary source

Lev Sakhnovich, “Comparison of Thermodynamic Characteristics in Ordinary Quantum and Classical Approaches and Game Theory”, arXiv:1010.4717 (2011).

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