The quantum-classical partition-function inequality

Let Zq(β,h)=n=1eβEn(h)Z_q(\beta,h)=\sum_{n=1}^{\infty}e^{-\beta E_n(h)} be the quantum statistical sum, where En(h)E_n(h) are the energy eigenvalues, and let

Zc(β)=eβH(p,q)dpdqZ_c(\beta)=\int\int e^{-\beta H(p,q)}\,dp\,dq

be the classical statistical sum for the Hamiltonian

H(p,q)=12mj=1Npj2+V(q).H(p,q)=\frac{1}{2m}\sum_{j=1}^{N}p_j^2+V(q).

Here h>0h>0 is Planck's constant, β>0\beta>0, and NN is the dimension of the coordinate space. Quantum-classical partition-function inequality. The inequality

(2πh)NZq(β,h)Zc(β)(2\pi h)^N Z_q(\beta,h)\leq Z_c(\beta)

is true for all h>0h>0 and β>0\beta>0. This extends the Wigner--Kirkwood classical-limit relation from the limit h0h\to0 to a proposed global inequality, but the source supplies no resolution of the conjecture.

Sources & referencesView supporting material

Primary source

Lev Sakhnovich, “Comparison of Thermodynamic Characteristics in Ordinary Quantum and Classical Approaches and Game Theory”, arXiv:1010.4717 (2011).

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