The quantum-classical partition-function inequality
The quantum-classical partition-function inequality
Let be the quantum statistical sum, where are the energy eigenvalues, and let
be the classical statistical sum for the Hamiltonian
Here is Planck's constant, , and is the dimension of the coordinate space. Quantum-classical partition-function inequality. The inequality
is true for all and . This extends the Wigner--Kirkwood classical-limit relation from the limit to a proposed global inequality, but the source supplies no resolution of the conjecture.
Sources & referencesView supporting material
Primary source
Lev Sakhnovich, “Comparison of Thermodynamic Characteristics in Ordinary Quantum and Classical Approaches and Game Theory”, arXiv:1010.4717 (2011).
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