The quantum-classical partition-function inequality
Let be the quantum statistical sum, where are the energy eigenvalues, and let
be the classical statistical sum for the Hamiltonian
Here is Planck's constant, , and is the dimension of the coordinate space. Quantum-classical partition-function inequality. The inequality
is true for all and . This extends the Wigner--Kirkwood classical-limit relation from the limit to a proposed global inequality, but the source supplies no resolution of the conjecture.
References
Primary source
Lev Sakhnovich, “Comparison of Thermodynamic Characteristics in Ordinary Quantum and Classical Approaches and Game Theory”, arXiv:1010.4717 (2011).
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